The reason your scheme will not work is not the purity. Of course a manufactured metal item will have more purity than the ore. Ore also has to be reduced. as the metal are present as cations.
The reason your scheme will not work is that smelting all the nickels and pennies will not yield you that much copper compared to the amount mined each and every year. See post #8 where I explained it to you in some detail.
Also, it is 1982, not 1984. And those account for at most 20% of pennies in circulation currently.
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