The balloon keeps doing what it was always doing - moving away from the applied force. 
An untethered balloon is not part of the accelerating system at all; it just stays where it was, and the car moves forward without it; from the POV of the passengers, it moves backwards. (in fact, it moves forwards quite a bit, due to friction with the roof of the vehicle, and due to the forward motion of the air inside the vehicle; but the car accelerates forwards faster than the balloon).
		
		
	 
This is just flat out wrong bilby.  I don't think that you understood the explanation of the experiment.  The air compresses in the back of the vehicle and pushes the balloon forward tethered or not.  The tether's horizontal force just stops the balloon from getting to the very front of the car.
I think that you understand it now since you mentioned the buoyancy in a post after this, so why can't you just admit that you were wrong?  This kind of behavior is so frustrating that I don't even like being on these forums anymore.